寤ｆキ(y猫)濉戣啝鍘熸枡閵峰敭sebs602浠ヤ笅鏄棞(gu膩n)浜�SEBS鐨勪竴浜涚浉闂�(gu膩n)浠嬬垂锛�
涓€銆�sebs602鏂板瀷鐔卞鎬у綀鎬ч珨SEBS锛�
SESB鐨勬敼鎬�:SEBS涓€鑸笉鍠崹(d煤)浣滃綀鎬ч珨鏉愭枡浣跨敤锛屼富瑕佹湁涓夊€�(g猫)鍘熷洜锛氫竴鏄�SEBS鑸囧偝绲�(t菕ng)鐨勭～鍖栨鑶犵浉姣�锛屽瓨鍦ㄥ墰鎬ч亷(gu貌)澶с€佸瘑搴﹂珮绛夌己榛�(di菐n)锛屼笖浣跨敤婧害銆佽€愭憾鍔戞€�銆佽€愭补鎬х瓑閫氬父涓嶅強鍌崇当(t菕ng)鐨勭～鍖栨鑶�锛涗簩鏄�SEBS鐨勭矘搴﹁純澶�锛屼笉鏄撳湪濉戞枡鎴愬瀷鍔犲伐瑷�(sh猫)鍌欎笂閫�(j矛n)琛屽姞宸�锛涗笁鏄�SEBS鍍�(ji脿)鏍兼槀璨�銆傚洜姝�锛岀偤澧炲姞SEBS鑸囪仛鍚堢墿鐨勭浉瀹规€�锛�SEBS缍�(j墨ng)甯告贩鍏ュ叾浠栫啽濉戞€у鏂欎締(l谩i)鍒跺緱杌熻唱(zh矛)鐨勫叡娣风墿锛屾墍鍒跺緱鐨勫叡娣风墿鍏锋湁娴佸嫊(d貌ng)鎬с€侀€忔槑鎬у拰鏌旈煂鎬х瓑澶氱ó鎬ц兘锛岀敤浜庡埗閫犲伐妤�(y猫)鐢ㄥ搧銆侀啱(y墨)鐧傚櫒鍏峰強閬�(y霉n)鍕�(d貌ng)鍣ㄦ潗涓�锛屾槸鐢ㄩ€斿唬娉涚殑鏂板瀷褰堟€ч珨鏉愭枡銆�
浜屻€�sebs602閵峰敭鐞嗗康锛氭澅鑾炲競寤ｆキ(y猫)濉戣啝灏堟キ(y猫)閵峰敭鍚勯宸ョ▼濉戞枡銆佺啽濉戞€у綀鎬ч珨銆侀€氱敤濉戞枡銆傞姺鍞悇澶у搧鐗屽師瑁濇柊鏂�銆傚叕鍙歌垏澶氬鐭冲寲鍏徃鏈夊悎浣滈棞(gu膩n)绯伙紝涓荤嚐(y铆ng)鍝佺墝鏈夛細寰峰湅(gu贸)鎷滆€�銆佸痉鍦�(gu贸)宸存柉澶�銆佸痉鍦�(gu贸)鏈楃洓銆佽嵎铇�DSM銆佺憺澹�EMS銆佺編鍦�(gu贸)鏉滈偊銆佺編鍦�(gu贸)?锛熸澗顒兼ⅷ?銆佺編鍦�(gu贸)鑸掔埦鏇笺€佺編鍦�(gu贸)娉扮绱�銆佹棩鏈笣浜�銆佹棩鏈嚭鍏�銆佹棩鏈鐞�銆佹棩鏈畤閮�銆侀煋鍦�(gu贸)宸ョ▼銆侀煋鍦�(gu贸)LG绛�?锛熸搮璧揗(f猫i)鎻愪緵鍘熸枡瑕�(gu墨)鏍兼浉锛堢墿鎬ц〃锛�銆�MSDS銆�SGS绛夌浉闂�(gu膩n)鐗╄唱(zh矛)璀夋槑璩囨枡锛屾墍鍞師鏂欏潎鐐哄師瑁濇鍝�锛岃唱(zh矛)閲忔湁淇濋殰锛屾杩庡墠渚�(l谩i)閲囪臣(g貌u)銆�
涓夈€�sebs602 鍘熷瓙鍔涢’寰彙鐮旂┒鏄熷瀷SEBS鑱氶泦楂旂殑琛ㄩ潰褰㈡厠(t脿i)璁婂寲锛�
鑱氬悎鐗╁垎瀛愰張?zh菙n)鎬北Y(ji茅)妲�(g貌u)鍠厓閫氶亷(gu貌)鍏卞児(ji脿)閸电浉浜掗€ｆ帴鑰屾垚锛屼竴鑸儏娉佷笅锛岃仛鍚堢墿澶у垎瀛愰張鍛堢窔鍨嬫(g貌u)閫�;鏀寲澶у垎瀛愮殑鍖栧(xu茅)鎬ц唱(zh矛)鑸囩窔鍨嬪ぇ鍒嗗瓙鐩镐技锛屼絾鏄敮鍖栧皪(du矛)鑱氬悎鐗╃殑鐗╃悊姗�(j墨)姊版€ц兘鍙婂姞宸ユ祦鍕�(d貌ng)鎬ф湁杓冨ぇ褰遍熆銆傜洰鍓�锛屾枃鐛�(xi脿n)鍫�(b脿o)閬撹純澶氱殑鏄窔鍨�SEBS婧舵恫鎴愯啘鍚庤仛闆嗛珨鐨勫舰鎱�(t脿i)浠ュ強閫欎簺鑱氶泦楂斿湪鍩虹墖琛ㄩ潰涓婂舰鎴愮殑澶氬昂搴﹁仛闆嗘厠(t脿i)绲�(ji茅)妲�(g貌u)鐨勭爺绌�锛屽苟鏈秹鍙婃槦鍨嬫敮鍖�SEBS鐨勭爺绌躲€備綔鑰呮摤鍒╃敤AFM鑰冨療鏃嬫秱浜庝簯姣嶅熀鐗囧舰鎴愮殑鏄熷瀷SEBS鑱氶泦楂旂殑琛ㄩ潰褰㈡厠(t脿i)锛岄€氶亷(gu貌)鏀硅畩?n猫i)鑺ゅ樋|(zh矛)閲忔績搴�銆佹憾鍔戠ó椤炪€佺啽铏曠悊婧害浠ュ強瓒呰伈娉㈣檿鐞嗕締(l谩i)鐮旂┒鑱氶泦楂旇〃闈㈠舰鎱�(t脿i)鐨勮畩鍖�锛屽苟灏囧叾鑸囩窔鍨�SEBS浣滃皪(du矛)姣旓紝鑰冨療涓嶅悓妲�(g貌u)閫�SEBS宓屾鍏辫仛鐗╁灏哄害褰㈡厠(t脿i)鐨勫奖闊垮洜绱�锛屼互鏈熶娇閫欎簺鍦栨鍖栬仛鍚堢墿褰㈡厠(t脿i)绲�(ji茅)妲�(g貌u)鑳芥噳(y墨ng)鐢ㄤ簬宓屾鍏辫仛鐗╃殑妯℃澘瑷�(sh猫)瑷�(j矛)涓€�
鍥�銆�sebs602 鍦栫墖灞曠ず
浜�銆佷笉鍚�SEBS 绲�(ji茅)妲�(g貌u)鑸囨€ц兘闂�(gu膩n)绯绘帰绌�sebs602锛�
Study of the Relationship Between Perbance and Structure of Different SEBS
CHEN Jia-yue, LI Yong-gang, CAI Bing,YIN Li-gang,
ZHU Xue-zhen, WANG Feng-gang, YIN Jing-hua*
锛�Weigao Holding Company Limited, Shandong Weihai 264210锛�
Abstract锛�The perbance of polymers is determined by its structure. In this paper, the structure of two kinds of styrene-ethylene/butylene-styrene (SEBS) block copolymers was analyzed by IR, 1HNMR, DSC and DMA, and the morphology and perbance of the infusion film prepared by these SEBS materials was characterized. The results showed that the content of the hard segment, the component and degree of unsaturation of the soft segment had effect on the perbance of the product.
Keywords锛�SEBS锛�Microstructure锛�Perbance
鍏€�SEBS鏀规€х€濋潚鐨勫埗鍌欒垏鎬ц兘鐮旂┒sebs602锛�
鐎濋潚娣峰悎鏂欐槸鍚勭礆(j铆)閬撹矾寤鸿ō(sh猫)鐢ㄦ潗涔嬩竴,杩戝勾渚�(l谩i),闅ㄨ憲鍏矾閬�(y霉n)杓歌矤(f霉)鑽疯秺渚�(l谩i)瓒婂ぇ,灏�(du矛)鐎濋潚缍滃悎鎬ц兘涔熸彁鍑轰簡鏇撮珮鐨勮姹�,鏀规€х€濋潚鑳芥湁鏁堝湴鏀瑰杽璺敤鎬ц兘,鍥犺€屽叾鐮旂┒鑸囨噳(y墨ng)鐢ㄨ秺渚�(l谩i)瓒婂彈鍒颁汉鍊戠殑闂�(gu膩n)娉�?鑻箼鐑�-涓佷簩鐑�-鑻箼鐑�(SBS)宓屾鑱氬悎鐗╂敼鎬х€濋潚鏄洰鍓嶆噳(y墨ng)鐢ㄨ純鐐哄唬娉涚殑鑱氬悎鐗╂敼鎬х€濋潚涔嬩竴,浣嗘槸鐢变簬涓嶉＝鍜岄嵉鐨勫瓨鍦�,SBS鏀规€х€濋潚鍦ㄨ純鐐烘儭鍔ｇ殑鍏夌啽姊濅欢涓嬫€ц兘涓嬮檷杓冨揩,妤靛ぇ鍦板奖闊夸簡閬撹矾浣跨敤澹藉懡.
涓�銆�sebs602 閲囪臣(g貌u)鑱�(li谩n)绯绘柟寮忥細
鑱�(li谩n)绯诲湴鍧€锛氬唬鏉辩渷鏉辫帪甯傛鏈ㄩ牠濉戣啝鍟嗗嫏(w霉)涓績
鑱�(li谩n)绯婚浕瑭�/寰俊锛�13412886878锛堥劎鐢燂級
鍌崇湡铏�(h脿o)纰硷細0769-82933089
楱拌▕ QQ锛�673160582
鍏�銆佸唬妤�(y猫)瑕栬--PA6涓婃紨鍙嶈綁(zhu菐n)澶ф埐 宸卞収(n猫i)閰拌兒姝㈣穼浼佺┅(w臎n) sebs602
11鏈�21鏃ヨ▕
11鏈堜紛濮嬶紝PA6銆佸繁鍏�(n猫i)閰拌兒甯傚牬(ch菐ng)骞句箮涓€閭婂€掔殑鐪嬬┖銆傚粻瀹跺皝鐩�锛岃部(m脿o)鏄撳晢浣庡児(ji脿)鎷嬭波鎴愮偤涓绘祦锛岃彲鏉卞父瑕�(gu墨)绱″垏鐗囦竴璺笅婊戯紝鎴嚦涓婂懆浜斾箣鍓�锛岄儴鍒嗕腑绮樺垏鐗囧凡璺岀牬17000鍏�/鍣稿ぇ闂�(gu膩n)銆�
浣嗗懆浜斾笂鍗堣捣锛岃鎯呯獊鐒跺嚭鐝�(xi脿n)閫嗚綁(zhu菐n)銆備竴鏂归潰鏄爯(y霉)鏈熶腑鐨勮妤�(y猫)搴曢儴渚�(l谩i)鑷�锛屽啀鑰�锛屽垏鐗囦笅娓稿伐寤犲鐒�(w煤)搴�(k霉)瀛�锛屽競鍫�(ch菐ng)寮曠櫦(f膩)澶ц(gu墨)妯℃斁閲忛噰璩�(g貌u)锛屼护甯歌(gu墨)绱�PA6鍒囩墖鍍�(ji脿)鏍肩灛闁撹澶у箙鎷夊崌锛屽伐寤犳柟闈㈠湪涓婂懆浜斿凡琛ㄩ湶鍑鸿(di脿o)鍍�(ji脿)婧�(zh菙n)鍌�銆�
鏈懆锛�PA6鍍�(ji脿)鏍兼剰鏂欎腑绌�(w臎n)姝ヤ笂琛屻€傛牴鎿�(j霉)鐢熸剰绀剧洠(ji膩n)娓�(c猫)鐨勫児(ji脿)鏍兼暩(sh霉)鎿�(j霉)渚�(l谩i)鐪�锛屼笂鍛ㄤ簲浠ヤ締(l谩i)锛�3鍊�(g猫)宸ヤ綔鏃�(11.17-11.21)PA6(涓矘甯歌(gu墨)绱�)婕插箙3.35%锛屽競鍫�(ch菐ng)蹇冩厠(t脿i)鐢卞急杞�(zhu菐n)寮�(qi谩ng)銆傝€�PA6鐨勫揩閫熷弽杞�(zhu菐n)涔熷皫(d菐o)鑷村師鏂欏繁鍏�(n猫i)閰拌兒姝㈣穼鍥炵┅(w臎n)锛屼粖鏃ユ恫楂斾富娴佸牨(b脿o)鐩ゅ凡鍥炲崌鑷�15600-15800鍏�/鍣搁檮杩戯紝鍥洪珨鍫�(b脿o)鐩や篃鎷夊崌浜嗚繎500鍏�/鍣歌嚦16200-16700鍏�/鍣�銆�
鐩墠鍒囩墖甯傚牬(ch菐ng)鍫�(b脿o)鍍�(ji脿)鏅亶鍫�(ji膩n)鎸�銆傚緸寤犲鏂归潰渚�(l谩i)鐪嬶紝鑿澅甯歌(gu墨)绱′富娴佸牨(b脿o)鐩や笂绉昏嚦18500鍏�/鍣稿乏鍙�锛岄珮閫熺础鐢变簬涔嬪墠璺屽箙鏈夐檺锛屾毇娉㈠嫊(d貌ng)涓嶅ぇ锛屼富娴佸牨(b脿o)鍍�(ji脿)鍙冭€�19500鍏�/鍣镐笂涓�銆�
