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[鎽� 瑕�]浠ョ啽濉戞€ц仛閰綀鎬ч珨(TPEE)鍜屼笝鐑吀閰鑶�(ACM)鐐哄師鏂欙紝鑱氫箼鐑簽鑳虹偤浜よ伅(li谩n)鍔�锛屽皪(du矛)TPEE/ACM 鐔卞鎬у綀鎬ч珨鐨勫埗鍌欏拰鎬ц兘閫�(j矛n)琛屼簡鐮旂┒銆傚皪(du矛)姣斾簡涓嶅悓纭寲楂旂郴鐨勪氦鑱�(li谩n)鑳藉姏锛岄€氶亷缍滃悎鍔涘(xu茅)鎬ц兘銆佽綁(zhu菐n)鐭╂祦璁婂剙銆佺啽閲嶅垎鏋愬剙鍜屾巸鎻忛浕閺″垎鍒ヨ〃寰佷簡TPEE/ACM 鐔卞鎬у綀鎬ч珨鐨勫姏瀛�(xu茅)鎬ц兘銆佹祦璁婃€ц兘銆佺啽鍒嗚В鎬ц兘鍜岀祼(ji茅)妲�(g貌u)銆�[闂�(gu膩n)閸佃]鐔卞鎬ц仛閰綀鎬ч珨锛涗笝鐑吀閰鑶�锛涚～鍖栬啝锛涘嫊(d貌ng)鎱�(t脿i)纭寲
浜�銆併€愮従(xi脿n)璨ㄤ緵鎳�(y墨ng)銆�tpee hytrel 鐔卞鎬ц仛閰綀鎬ч珨鐨勭敓鐢�(ch菐n)鎶€琛�(sh霉)鍙婃噳(y墨ng)鐢細
TPEE鐨勪娇鐢ㄦ韩搴﹁寖鍦嶅锛屽湪婧害闄嶈嚦-70鈩冩檪(sh铆)锛�TPEE浠嶇劧涓嶆渻(hu矛)璁婅剢锛岃€愬瘨鎬ч潪甯稿ソ锛�-40鈩冪殑姊濅欢涓嬭兘闀�(zh菐ng)鏈熶娇鐢�锛屽叾娌栨搳寮�(qi谩ng)搴﹂仩(yu菐n)楂樹簬鍏朵粬TPE锛�120鈩冧互涓婏紝TPEE鐨勬媺浼稿挤(qi谩ng)搴﹂仩(yu菐n)鍕濅簬TPU锛�150鈩冩檪(sh铆)锛屼篃鑳戒繚鎸佹サ濂界殑鍔涘(xu茅)鎬ц兘锛�TPEE鐨勭煭鏈熶娇鐢ㄦ韩搴︽洿楂橈紝鍙互閬╂噳(y墨ng)姹借粖鐢熺敘(ch菐n)绶氫笂150~160鈩冪殑鐑樻紗婧害銆傝垏鍏朵粬TPE鐩告瘮锛�TPEE鐨勮€愮啽鎬ц兘鏈€楂�锛屼笖鍦ㄩ珮銆佷綆婧浠朵笅鐨勫姏瀛�(xu茅)鎬ц兘鎼嶅け灏�銆�TPEE鍦ㄥ婧浠朵笅鑰愰吀銆佸牽銆佽兒鍙婁簩閱囬鍖栧悎鐗╃瓑澶у鏁�(sh霉)妤垫€ф恫楂�锛屽叾鑰愬寲瀛�(xu茅)钘ュ搧鑵愯潟鐨勮兘鍔涢毃纭害鐨勬彁楂樿€屾彁楂�銆�TPEE鍏锋湁鍎�(y艒u)鐣扮殑鑰愭补鎬�锛岀噧娌规徊閫忔€у儏鐐烘隘涓佹鑶犮€佷竵鑵堟鑶�銆佹隘纾哄寲鑱氫箼鐑瓑鑰愭补姗¤啝鐨�1/3~1/300銆�TPEE灏�(du矛)澶у鏁�(sh霉)鐨勬湁姗�(j墨)婧跺姂銆佺噧鏂欏強姘ｉ珨鐨勬姉婧惰劰鎬ц兘鍜屾姉?ji茅)B閫忔€ц兘杓冨ソ銆�
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鍥�銆併€愮従(xi脿n)璨ㄤ緵鎳�(y墨ng)銆�tpee hytrel 鐢�(ch菐n)鍝佸湒鐗囦俊鎭細
浜�銆併€愮従(xi脿n)璨ㄤ緵鎳�(y墨ng)銆憈pee hytrel 鐔卞鎬ц仛閰綀鎬ч珨鐨勭爺绌堕€�(j矛n)灞曡垏鎳�(y墨ng)鐢細
杌岄亾浜ら€�:TPEE鎿佹湁鍎�(y艒u)鐣扮殑鎶楃柌鍕炴€с€佽€愬绺畩褰㈡€у拰鑰愮挵(hu谩n)澧冧镜铦曟€�锛屼笖杓夎嵎鑳藉姏鏇撮珮锛屽湪-40鈩冿綖150鈩冩檪(sh铆)锛�TPEE鐨勬€ц兘鍙繚鎸佷竴鑷�锛屽湪杌岄亾娓涙尟銆佽粚閬撹垏杌婅紱鐨勭珐娌�銆佹笡鎸瓑鏂归潰鎴愬姛鐛插緱鎳�(y墨ng)鐢�銆傝粖閴ょ珐娌栬缃槸鐢ㄤ簬浣胯粖杓涜垏杌婅紱銆佹(j墨)杌婅垏鍕�(d貌ng)杌婄浉浜掗€ｆ帥锛屽偝閬炵壗寮曞姏銆佸埗鍕�(d貌ng)鍔涘苟绶╁拰绺卞悜娌栨搳鍔涚殑閮ㄤ欢锛屽叾浣跨敤鐗规€ц姹傚叿鏈夎€愰珮閫�?z猫ng)_鎿婃垨鍚告敹鍎�(ch菙)瀛樺姞澶ф矕鎿婄殑鑳藉姏锛岀劧鑰屼互寰€涓昏閲囩敤鐨勯嫾璩�(zh矛)褰堢哀绲�(ji茅)妲�(g貌u)鎴栨鑶犵珐娌栧櫒鐢变簬鑳介噺鍚告敹鑳藉姏绛夊師鍥犲凡涓嶉仼鎳�(y墨ng)鐩墠鐨勯珮閫熼惖璺亱(y霉n)杓搁珨绯�銆傜浉姣旇純鑰岃█锛�TPEE绶╂矕浠舵€ц兘绌�(w臎n)瀹�锛岀祼(ji茅)妲�(g貌u)绨�(ji菐n)鍠€佺敤閲忓皯銆佽唱(zh矛)閲忚紩锛屽惛鏀剁巼楂�銆佸彲椤憲鎻愰珮绶╂矕瀹归噺锛屾淇柟渚�锛岃兘閬╂噳(y墨ng)閻佃矾閬�(y霉n)杓搁噸杓�銆侀珮閫熺殑闇€瑕�銆傛垜鍦�(gu贸)澶хЕ閻佃矾涓婄殑閲嶈級璨ㄨ粖灏遍噰鐢ㄤ簡TPEE绶╂矕鍣�锛屾€ц兘鐩哥暥(d膩ng)绌�(w臎n)瀹氥€�
鍏�銆併€愮従(xi脿n)璨ㄤ緵鎳�(y墨ng)銆�tpee hytrel PP-TPEE 鍏辨贩鐗╃殑绲�(ji茅)鏅舵€ц兘锛�
Reseach on the Crystallization Behavior of PP-TPEE Blends
ZHOU Deng-fei, JIANG Jia-li, WU Xiao-hua, QIAN Yang, QIN Yan-fen, WANG Xiu-hua* (Textile Fiber Materials and Processing Technology Local Joint Engineering Laboratory of the National,Zhejiang Sci-Tech University, Hangzhou 310018, Zhejiang, China) Abstract: In this paper, polypropylene-g-glycidylmethacrylate (PP-g-GMA) was used as the compatilizer for polypropylene-thermal polyester elastomer (PP-TPEE) blends, the crystallization behavior of blends was investigated by X-ray diffracmeter(XRD) and differential scanning calorimeter(DSC). The result of XRD showed that the addition of TPEE and PP-g-GMA changed the crystal facet beter of PP, increased crystal plane spacing. The result of DSC showed that the addition of TPEE increased the heat crystallization temperature of the blend, decreased the crystallinity. As the increase of the content of PP-g-GMA, the crystallinity of the blend decreased further. The heat crystallization temperature of pure PP and PP-TPEE blends were gradually decreased with the increase of DSC cooling rate. Key words: polypropylene, thermal polyester elastomer, blending, crystallization, behavior
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